Al-Ni-Mn casting alloy for automotive and aerospace structural components

ABSTRACT

There is claimed an Al—Ni—Mn based alloy for die casting, squeeze casting, permanent mold casting, sand casting and/or semi-solid metal forming. The composition of this alloy includes, by weight percent: about 0.5-6% Ni, about 1-3% Mn, less than about 1% Fe, less than about 1% Si, less than about 0.3% Ti, and less than about 0.06% B, the balance Al, incidental elements and impurities. It is suitable for aerospace and automotive cast parts.

RELATED APPLICATIONS

[0001] This application claims the benefit of U.S. Provisional Patent Application Ser. No. 60/345,182 filed on Dec. 21, 2002 and entitled “An Al—Ni—Mn Casting Alloy for Automotive and Aerospace Structural Components”, the disclosure of which is fully incorporated by reference herein.

FIELD OF THE INVENTION

[0002] This invention relates to the field of aluminum-based casting alloys. It further relates to automotive and aerospace parts made from such alloys.

BACKGROUND OF THE INVENTION

[0003] Most aluminum casting alloys need to be solution heat treated, quenched, and artificially aged to achieve adequate properties for automotive and aerospace structural applications. The processes of solution heat treating and quenching not only increase operational and capital costs but also induce part distortion, which then requires adding a straightening step to the overall manufacturing process. That straightening step is time-consuming and a high cost operation that greatly limits the applications of cast Al alloys.

[0004] Recently, some non-heat treatable (or “NHT”) alloys were developed and implemented in production. Those alloys can be used in either an F-temper or T5 condition. Unfortunately, those alloys tend to have much less castability than alloys required in a T6-type temper.

SUMMARY OF THE INVENTION

[0005] The present invention consists of an Al—Ni—Mn based alloy for die casting, squeeze casting, permanent mold casting, sand casting and/or semi-solid metal forming. Preferred embodiments of this alloy include the following compositional additions, all in weight percent: about 0.5-6% Ni, about 1-3% Mn, less than about 1% Fe, less than about 1% Si, less than about 0.3% Ti, and less than about 0.06% B, the balance Al, incidental elements and impurities. On a more preferred basis, this alloy composition consists essentially of about 3.5-4.5% Ni, about 1.5-2.5% Mn, less than about 0.1% Fe, less than about 0.1% Si, less than about 0.15% Ti, and less than about 0.03% B, the balance Al and incidentals.

DESCRIPTION OF PREFERRED EMBODIMENTS

[0006] When referring to any numerical range of values herein, such ranges are understood to include each and every number and/or fraction between the stated range minimum and maximum. A range of about 0.5-6 wt. % nickel, for example, would expressly include all intermediate values of about 0.6, 0.7 and 0.9 % Ni, all the way up to and including 5.95, 5.97 and 5.99 wt. % nickel. The same applies to each other numerical property and/or elemental range set forth herein.

[0007] The invention alloy decribed herein has the following benefits: (a) excellent castability including high fluidity and low hot cracking tendency, properties which are not found in other NHT Al alloys; and (b) good tensile properties without any heat treatments. The alloy composition of this invention eliminates the need for SHT, quench and aging processes, while also showing good fracture toughness in the as-cast condition.

[0008] Several alloy compositions were comparatively cast, using permanent mold castings, from which the following properties were measured: TABLE 1 Mechanical Properties (Tensile), Hardness (HB) and Hot Cracking Index (HCI) for Several Al—Ni—Mn Alloys in As-Cast Condition Samp UTS YS % HCI, # Composition (Mpa) (Mpa) Elong HB mm 1 Al-2Ni-2Mn-0.1Ti-0.02B 159 82 24 56 4 2 Al-2.5Ni-2Mn0.3Zr-0.3Cr 180 100 17 65 4 3 Al-4Ni-2Mn-0.1Ti-0.02B 208 129 16 62 <4

[0009] Another set of alloy compositions was comparatively cast and evaluated. The results of Kahn Tear tests performed thereon were as follows: TABLE 2 Kahn Tear testing of Two Preferred Embodiments Alloy Composition UPE (KJ/m2) 1 Al-3.85 Ni-1.91 Mn-0.02 Ti-0.002B 90 2 Al-3.88 Ni-1.98 Mn-0.1 Ti-0.02B 115

[0010] From this table, it was concluded that lower titanium and/or boron contents had a negative impact on Kahn Tear properties.

[0011] The influence of nickel on hot cracking index (HCI) and mechanical properties of several individually cast compositions containing 2% Mn (as-cast) was then mapped for comparison. Also included were representative samples of cast alloy A356 (Aluminum Association designation). TABLE 3 Ni content effect on Hot Cracking Index (HCI) and Mechanical Properties (Tensile) and % Elongation Before corrosion test After corrosion test UTS Elong UTS Elong % Ni HCI, mm MPa % MPa % 0 12 98 36 101 — 0.5 4 121  9 — — 1 4 146 13 141 16 2 4 170 — 4 4 201  8 191  7 A356.0 4 186 — 169  6

[0012] From this table, it can be seen that a minimum of around 0.5 wt. % Ni is needed to achieve good castability (HCI=4 mm). In addition, this table showed that overall corrosion resistance does not appear to be significantly affected by total Ni content.

[0013] The role of ancillary elements on the mechanical properties (tensile testing) of Al-4Ni-2Mn alloy samples was next evaluated. For this comparison, all samples were machined from 22 mm diameter cast specimens. TABLE 4 Before corrosion test After corrosion test UTS, TYS, Elong., UTS, YS, Elong, Alloy Composition ## MPa MPa % MPa MPa % A356.0 7Si 0.3Mg 1 193 98 5.7 184 96 5.0 2 F temp 193 106 5.7 170 112 4.0 3 F temp 192 105 6.0 164 103 4.7 4 F temp 185 94 6.7 168 98 4.7 avg 191 101 6.0 172 102 4.6 A 2Ni2Mn0.1Ti(B) 1 157 82 20.0 148 79 17.0 2 F temp 154 81 20.7 151 84 22.7 3 F temp 152 79 24.3 154 83 20.7 4 F temp 153 79 20.7 152 84 19.7 avg 154 80 21.4 151 83 20.0 B 4Ni2Mn0.1Ti(B) 1 174 103 17.3 170 98 15.0 2 F temp 173 97 18.0 171 95 17.3 3 F temp 177 95 15.6 169 91 13.0 4 F temp 172 95 15.0 170 101 16.0 avg 174 98 16.5 170 96 15.3 C 2Ni2Mn0.1Ti(B) + 1 168 81 18.3 159 79 15.3 0.2Fe0.1Si 2 F temp 163 81 18.3 159 94 17.7 3 F temp 168 84 19.7 153 82 13.3 4 F temp 159 81 16.0 155 81 15.7 avg 165 82 18 157 84 16

[0014] From this data, it was observed that higher strengths can be achieved via higher Ni contents but that no significant change in overall corrosion resistance was found. TABLE 5 Effect of Ancillary elements in 4% Ni, 2% Mn Invention alloys UPE TYS UTS Elong HCI KJ/ Comp. Fe Si Ti B MPa MPa % mm m2 A-1 <0.05 <0.05 0.0 0.0 — — — 4 2 <0.05 <0.05 0.05 0.01 — — — 4 3 <0.05 <0.05 0.1 0.02 99 199 16 4 80 4 <0.05 0.1 0.1 0.02 96 201 15 6 62 5 <0.05 0.3 0.1 0.02 96 209 13 6 46 6 <0.05 0.5 0.1 0.02 98 217 12 10 40 7 <0.05 0.7 0.1 0.02 93 181 5 14 34 8 <0.05 0.9 0.1 0.02 93 201 7 >16 32 B-1 0.1 <0.05 0.1 0.02 100 201 11 4 2 0.2 <0.05 0.1 0.02 94 193 15 <6 3 0.2 0.1 0.1 0.02 4 4 0.3 0.1 0.1 0.02 4 5 0.3 0.2 0.1 0.02 6 6 0.5 0.2 0.1 0.02 <6 7 0.7 0.2 0.1 0.02 6 8 0.9 0.2 0.1 0.02 10

[0015] From this data, it was interpreted that hot cracking tendencies (as evidenced by larger HCI values) tended to increase with increasing Si content. Hot cracking tendencies are relatively less sensitive to Fe contents, as compared to Si levels. Finally, the elongation and propagation energy values decrease with increasing Si content.

[0016] A more preferred alloy composition according to this invention consists essentially of: about 3.7-4.2 wt. % Ni, about 1.7-2.2 wt. % Mn, up to about 0.1 wt % Fe and up to about 0.1 wt. % Si, about 0.08-0.15 wt. % Ti, about 0.01-0.03 wt. % B, the balance aluminum.

[0017] Having described the presently preferred embodiments, it is to be understood that the invention may be otherwise embodied within the scope of the appended claims. 

What is claimed is:
 1. An aluminum casting alloy composition that includes: about 0.5-6 wt. % Ni, about 1-3 wt. % Mn, less than about 1 wt. % Fe, less than about 1 wt. % Si, less than about 0.3 wt. % Ti, and less than about 0.06 wt. % B, with incidental elements and impurities.
 2. The alloy composition of claim 1 which contains about 3.5-4.5 wt. % Ni.
 3. The alloy composition of claim 2 which contains about 3.7-4.2 wt. % Ni.
 4. The alloy composition of claim 1 which contains about 1.5-2.5 wt. % Mn.
 5. The alloy composition of claim 4 which contains about 1.7-2.2 wt. % Mn.
 6. The alloy composition of claim 1 which contains about 0.08-0.15 wt. % Ti.
 7. The alloy composition of claim 1 which contains about 0.01-0.03 wt. % B.
 8. The alloy composition of claim 1 which contains up to about 0.25 wt % Fe.
 9. The alloy composition of claim 8 which contains up to about 0.1 wt % Fe.
 10. The alloy composition of claim 1 which contains up to about 0.25 wt. % Si.
 11. The alloy composition of claim 10 which contains up to about 0.1 wt. % Si.
 12. An aerospace structural component cast from an alloy composition that includes: about 0.5-6 wt. % Ni, about 1-3 wt. % Mn, less than about 1 wt. % Fe, less than about 1 wt. % Si, less than about 0.3 wt. % Ti, and less than about 0.06 wt. % B, the balance aluminum, incidental elements and impurities.
 13. The aerospace component of claim 12 wherein said composition consists essentially of: about 3.5-4.5 wt. % Ni, about 1.5-2.5 wt. % Mn, up to about 0.25 wt. % Fe, up to about 0.25 wt. % Si, about 0.08-0.15 wt. % Ti, up to about 0.05 wt. % B, the balance aluminum, incidental elements and impurities.
 14. The aerospace component of claim 13 wherein said composition consists essentially of: about 3.7-4.2 wt. % Ni, about 1.7-2.2 wt. % Mn, up to about 0.1 wt. % Fe, up to about 0.1 wt. % Si, about 0.08-0.15 wt. % Ti, about 0.01-0.03 wt. % B, the balance aluminum, incidental elements and impurities.
 15. An automotive structural component cast from an alloy composition that includes: about 0.5-6 wt. % Ni, about 1-3 wt. % Mn, less than about 0.1 wt. % Fe, less than about 0.1 wt. % Si, less than about 0.3 wt. % Ti, and less than about 0.06 wt. % B, the balance aluminum, incidental elements and impurities.
 16. The automotive component of claim 10 wherein said composition consists essentially of: about 3.5-4.5 wt. % Ni, about 1.5-2.5 wt. % Mn, up to about 0.25 wt. % Fe, up to about 0.25 wt. % Si, about 0.08-0.15 wt. % Ti, up to about 0.05 wt. % B, the balance aluminum, incidental elements and impurities.
 17. The automotive component of claim 10 wherein said composition consists essentially of: about 3.7-4.2 wt. % Ni, about 1.7-2.2 wt. % Mn, up to about 0.1 wt. % Fe, up to about 0.1 wt. % Si, about 0.08-0.15 wt. % Ti, about 0.01-0.03 wt. % B, the balance aluminum, incidental elements and impurities. 